You can use the Rearrange Commands dialog box to do this. To get there: Launch the Tools->Customize dialog. Now select the Commands Tab. Click on the Rearrange commands… button, and this will launch the dialog that will help you with arranging your
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Read the complete post at http://blogs.iis.net/webdevelopertips/archive/2009/07/23/tip-90-did-you-know-how-to-rearrange-menu-items-in-visual-web-developer.aspx